Physicists have simulated the structure of a new material based on fullerite and single crystal diamond to show how this material can obtain ultrahigh hardness. This discovery allows the estimations the potential conditions for obtaining ultrahard materials. The results were published in the Carbon journal.
Fullerite generally is a molecular crystal with fullerene molecules at its lattice nodes. Fullerenes are a form of molecular carbon where carbon atoms form a sphere. It was first synthesized over thirty years ago, and its discovery was awarded with the Nobel Prize. Carbon spheres in fullerite may be packed in different ways, and the hardness of the material strongly depends on how the fullerenes are connected to each other.
A group of scientists from MIPT, Skoltech, NUST MISIS and the Federal State Budgetary Scientific Institution Technological Institute for Superhard and Novel Carbon Materials (FSBSI TISNCM, Moscow, Troitsk) headed by Prof. Leonid Chernozatonskii from the Institute of Biochemical Physics (IBCP) of the Russian Academy of Sciences, and Pavel Sorokin, Doctor of Physical and Mathematical Science, leading researcher at NUST MISIS Inorganic Nanomaterials Laboratory, and professor at MIPT, managed to explain why fullerite becomes an ultra-hard material.
“When we started to discuss this idea, I was working at TISNCM. There, in 1998, a group of scientists headed by Vladimir D. Blank obtained a new material based on fullerenes — ultrahard fullerite, or ‘tisnumit’. According to the measurements, this new material could scratch diamond, that is, it was in fact harder than diamond”, remarked Alexander Kvashnin, Candidate of Physics and Mathematics, the main author.
The obtained substance was not single crystal material; it contained amorphous carbon and 3D-polymerized molecules of С60. Still, its crystal structure is not completely determined. The fullerene molecule has excellent mechanical rigidity. At the same time, the fullerite crystal is quite a soft material under normal conditions, but becomes harder than diamond under pressure (due to the 3D polymerization). Although this material has been synthesized and studied for more than 20 years now, the reason why it becomes ultrahard is still unknown. There is a number of models that have been developed to explain how fullerenes can be polymerized into fullerite.
One of the models was proposed by Prof. Leonid A. Chernozatonskii. The
Alexander Kvashnin remarks, “We based our analysis on that model and the experimentally known fact that if you apply high pressure, more than 10 GPa to fullerene powder, and heat it above 1800 К, you obtain a polycrystalline diamond. The idea was to combine these two facts. On the one hand, a super-hard fullerite material, and on the other hand, under pressure, fullerenes turn into a polycrystalline diamon”.
The scientists suggested that under pressure, part of the fullerite turned into diamond, while the other part remained as fullerite, but in a compressed state within the diamond. To simplify the model, the fullerite crystal structure proposed by Prof. Chernozatonskii was taken and placed inside a single crystal diamond. Then this composite material was studied. The idea was that fullerite inside diamond should be compressed. It is known that in the compressed state, the elastic and mechanical properties of the material would increase. And diamond would act as a shell, which keeps the compressed fullerite inside to preserve all those properties. In the study, they first analysed small models containing 2.5 nm fullerite grain inside the 1 nm thick diamond shell. However, such a small model did not comply with the experimental data. Then the researchers started modelling the composites, where the size of fullerite was increased up to 15.8 nm, and the thickness of diamond shell remained the same. The changes in the
“The developed model will help us to understand the nature of its unique properties and to help to systematically synthesize the new ultra-hard carbon materials, as well as to contribute to the further development of this promising field of science”, said Pavel Sorokin, Doctor of Physical and Mathematical Science, head of the project.
Fullerite itself is not very hard; its bulk modulus is 1.5 times less than that of diamond. But when it’s compressed, its bulk modulus increases dramatically. To preserve this enhanced bulk modulus, the fullerite should always remain in such a compressed state. Using the results of simulations, the scientists can conduct targeted experiments to obtain an ultra-hard material.